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Erscheinungsjahr: 
2019
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[Journal:] Energy Reports [ISSN:] 2352-4847 [Volume:] 5 [Publisher:] Elsevier [Place:] Amsterdam [Year:] 2019 [Pages:] 357-363
Verlag: 
Elsevier, Amsterdam
Zusammenfassung: 
Nano-crystalline synthetic gismondine modified via cation exchange has been utilised as a highly active and selective catalyst for the production of biofuel. In comparison with low silica zeolites FAU and LTA, K-form of gismondine, based on the maximum aluminium P (MAP) zeolite, exhibited a significant improvement in catalytic performance in the methanolysis of bio-oil, which can be attributed to its nano-particle morphology and high basicity associated with the high Al content and high degree of ion exchange, as demonstrated by the TEM, XRD, TGA, NMR, XPS and CO2-TPD studies. To the best of our knowledge, this is the first report on a successful catalytic application of basic K-MAP zeolite.
Schlagwörter: 
Transesterification
Basic sites
Nanostructured catalysts
Synthetic gismondine
Zeolites
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